inorganic-chemistry

Ancient Roman buildings, bridges and aqueducts have survived for thousands of years, and scientists have long wondered why their concrete has proved so durable. Now, lessons from Roman construction are being used to develop modern concrete that can repair small cracks on its own. MIT Associate Professor Admir Masic has spent years studying the chemistry […] The post Ancient Roman Secret Could Mak…

A modular synthetic route has been developed to prepare a new series of cationic ruthenium(II) complexes with electron-withdrawing 1,2-diacylcyclopentadienyl ligands. The 2-acyl-6-hydroxyfulvenes were synthesized from cyclopentadienide and acyl chlorides and converted to Tl(I) cyclopentadienyl salts using Tl 2 SO 4 /KOH. Transmetalation with [Ru(η 6 -p-cymene)(μ-Cl)Cl] 2 followed by PF 6 − metath…

A new approach to 5,5-fused heterocyclic derivatives of cyclopentadienylmanganese tricarbonyl and pentamethylruthenocene is presented. 1,2-Dicarbophenoxycyclopentadienyl complexes of manganese and ruthenium were hydrolyzed to 1,2-dicarboxylic acids. Oxalyl chloride converted the acids to chlorocarbonyls, which reacted with bis(trimethylsilyl)sulfide to give the cyclopentadienyl-fused thioanhydrid…

Ferrous ions in four-coordinate environments are common in protein structures, synthetic catalysts, and molecular magnets. The 3 d 6 configuration of high-spin Fe­(II) imparts an S = 2 ground state, whose analysis using conventional spectroscopic methods is often hindered by substantial zero-field splitting (ZFS). Herein, we provide detailed electronic-structure descriptions for [Fe II X­(Tp t Bu…

Gold(I) complexes have traditionally been limited to linear two-coordinate geometries (L-Au-L), exemplified by the clinically approved gold drug, auranofin. Although ligand engineering offers opportunities to expand the coordination environment of Au(I), the therapeutic potential of three-coordinate gold(I) complexes remains largely unexplored. This dissertation tests the hypothesis that rational…

Nature Communications, Published online: 10 August 2026; doi:10.1038/s41467-026-76517-0 Spin polarization plays a pivotal role in heterogeneous catalysis, but the precise construction of active sites with tailored spin states remains challenging. Here, the authors regulate the oxide mixology of precursor materials to tune the spin polarization of ferromagnetic cobalt centers in nitride catalysts,…

Washing soda, known chemically as sodium carbonate, is one of the oldest cleaning agents in the home. It appears in DIY laundry detergent recipes and commercial powders alike, where it softens water, lifts grease, and boosts the cleaning power of soap. The compound is inexpensive, easy to find in the laundry aisle, and useful far […] The post What Is Washing Soda? Uses, Chemistry, and How to Make…

Nature Communications, Published online: 05 August 2026; doi:10.1038/s41467-026-76406-6 Transition-metal oxides offer a low-cost alternative to precious metals for environmental catalysis, yet CO oxidation under humid and sulfur-laden conditions remains a challenge due to rapid catalyst poisoning. Here, the authors report an atomic dispersion of Ti-decorated MnOx-Fe2O3 catalyst with excellent act…

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