Practical and divergent electrochemical access to thiocarbamoyl fluorides and N -trifluoromethyl amines from secondary amines

Nature Communications, Published online: 20 June 2026; doi:10.1038/s41467-026-74660-2 The authors report a practical and divergent electrochemical method for converting simple secondary amines into thiocarbamoyl fluorides and N-trifluoromethyl amines, proceeding under mild, open-air conditions without solvent drying, degassing, inert atmosphere, or stoichiometric silver reagents.