Lithium storage mechanisms and kinetics in MOF-based anodes: from pristine frameworks to derived materials for high-performance lithium-ion batteries
Dongfang Shi
Metal-organic frameworks (MOFs) and their derivatives are found to be promising lithium-ion battery (LIB) anodes, yet their complex lithium storage mechanisms and kinetic behaviors remain insufficiently understood. In this review, lithium storage mechanisms in LIB anodes are systematically summarized, distinguishing between ligand- and metal-centered redox in pristine MOFs, and conversion, alloying, and host storage in MOF-derived materials. Pseudocapacitive contributions in bridging battery-typ