ABSTRACT The state‐of‐art commercial polymeric adhesives are mainly petroleum‐based, non‐biodegradable and not tolerant of low temperature, severely limiting their applications in extremely cold regions. Current research efforts focus on development of sustainable and biodegradable polyester‐based adhesives. However, nearly all the reported polyester‐based adhesives were used at room temperature, and the innovative functional polyester‐based adhesives with low‐temperature‐resistance are very rar