A Bipolar Integrated Electro‐Chemocatalysis System for Continuous‐Flow Paired Synthesis of Cyclohexanone Oxime at Industrial‐Relevant Current Density

ε-Caprolactam production critically depends on cyclohexanone oxime (CHO), yet its sustainable synthesis remains constrained by the handling and utilization of hydrogen peroxide (H₂O₂). Here, we developed a bipolar integrated electro-chemocatalysis system (BIECS) that enables continuous-flow paired CHO synthesis under ambient conditions with unprecedented efficiency. Using oxygen-vacancy-enriched bismuth oxide nanofibers as a bifunctional electrocatalyst, the system simultan