[{"_1":2,"_3":-5,"_4":-5},"loaderData",{"_5":6},"actionData","errors","oa-article--id--slug-",{"_7":8,"_9":10},"article",{"_11":12,"_9":10,"_13":14,"_15":16,"_17":18,"_19":20,"_21":22,"_23":-5,"_24":-5,"_25":26,"_27":28,"_29":30,"_31":32,"_33":-5,"_34":35,"_36":37,"_38":39,"_40":-5},"server","openalex","id","W7155523322","contentType","paper","title","Iminophosphonamido-Supported Plumbyliumylidenes: Structural Effects of Counter Anions and Lewis Acid Catalysis","url","https://doi.org/https://doi.org/10.1021/acs.inorgchem.6c00589","doi","https://doi.org/10.1021/acs.inorgchem.6c00589","summary","Two-coordinate plumbyliumylidene ions constitute a rare class of highly electron-deficient cationic Pb(II) species. Herein, we report the synthesis and structural characterization of iminophosphonamido-supported plumbyliumylidene ions bearing two different borate counteranions, {B[(4-^tBuMe₂Si)C₆F₄]₄}^- and [B(C₆F₅)₄]^-. Single-crystal X-ray analyses reveal pronounced ion-pairing eff","imageUrl","imageWidth","publishedAt","2026-04-24T00:00:00.000Z","authors",[43,44,45,46,47],"sourceId","1889","sourceName","Inorganic Chemistry","sourceLogoUrl","citationCount",0,"isOpenAccess",false,"tags",[41,42],"relevanceScore","Organoboron and organosilicon chemistry","Organic Chemistry",{"_48":57,"_11":58},{"_48":55,"_11":56},{"_48":53,"_11":54},{"_48":51,"_11":52},{"_48":49,"_11":50},"name","Daisuke Hashizume","A5009162025","Kei Ota","A5083291487","Kazuki Nakaya","A5016551586","Norio Nakata","A5061347192","Yugo Kazama","A5110561598"]