ABSTRACT Many scientists would have no doubt that water droplets tend to be firmly adhered to hydrophilic surfaces. Contrary to this common belief, we have succeeded in preparing surfaces that are statically very hydrophilic but exhibit surprising water slipping performance. These surfaces were prepared through a chemisorption of ethoxy‐terminated polyethylene glycol (PEG) organosilane (Si‐PEG‐Si) and subsequent alkali‐treatment. We prepared Si‐PEG‐Si‐derived monolayers by varying Si‐PEG‐Si conc
