The synthesis of a carbon-free analog of ferrocene has been a long-standing goal in inorganic chemistry. We report here the preparation and crystallographic characterization of the carbon-free sandwich complex [Os(η5-B5H10)2], which is qualitatively similar to ferrocene in structure and bonding. The metal-ring bonding is much stronger in [Os(η5-B5H10)2], owing to rehybridization of the π molecular orbitals br