Bright Dual-Phase Organic Luminescence from Zero-Dimensional Lead Halide Hybrids via Sensitized Thermally Activated Delayed Fluorescence for Multifunctional Applications

Metal halide hybrids have long celebrated their halometallate moieties as the luminescent center, leaving organic cations behind. Although the thermally activated delayed fluorescence (TADF) strategy has enabled efficient solid-state organic emitters, the complex molecular design required for TADF emitters has limited their facile integration into metal halide hybrid architectures. Here, we demonstrate a versatile strategy wherein a nonemissive organic moiety (benzyltributylammonium) is incorpor