The knowledge of different types of anion-binding modes offered by π-acidic HAT(CN)6 and resorcinol-like double proton donors was successfully applied to construct unprecedented ternary {[HAT(CN)6];[PG];[X-]2} (HAT(CN)6 = 1,4,5,8,9,12-hexaazatriphenylene-hexacarbonitrile, PG = phloroglucinol; X = Cl, Br) synthons both in the solid state and in solution. These systems feature an adaptative coexistence of anion-π, hydrogen bonding, and π-π int
Hierarchy and Synergy of Anion‐π, Hydrogen Bonding and π‐π Interactions in Multicomponent Ionic Hybrid Architectures
Dorota Glosz·Robert Podgajny·Joachim Grzybowski·Monika Srebro‐Hooper·James Hooper·Bogdan Musielak·Tadeusz M. Muzioł·Aleksandra Żabińska