This study employs QCD sum rules to predict the masses and residues of spin- 3 2 doubly heavy baryons including two heavy quarks (c and/or b) and one light quark, specifically focusing on Ξ c c * , Ξ b c * , Ξ b b * , Ω c c * , Ω b c * and Ω b b * . Our study provides results for the ground state (1 S ), first orbital excitation (1 P ), and the first radial excitation (2 S ), within a consistent theoretical framework. In addition to mass spectra, we provide residue calculations as well. The calc