First information on the time-like electromagnetic structure of baryons in the second resonance region has been obtained from measurements of dielectron (e+ e-) invariant-mass and angular distributions in the quasi-free reaction ππ- p \rightarrow n e+ e- at sπp\sqrt{s_{πp}} = 1.49 GeV with the High Acceptance Di-Electron Spectrometer (HADES) at GSI using the pion beam impinging on a CH2_2 target. We find a total cross section σσ = 2.97 ±\pm 0.07data ±\pm 0.21acc ±\pm 0.31Zeff μμb. In com