Integrating Dissociating Stators and Conducting Rotors Within an Amphidynamic COF‐Based Solid‐State Polymer Electrolyte for Rapid and Consecutive Li + Transport

Solvent-free solid polymer electrolytes (SPEs) suffer from sluggish and discontinuous Li⁺ transport. Although high-polarity fillers enhance dissociation, liberated Li⁺ tends to be trapped on filler surfaces due to the spatial and dynamic mismatches, hindering Li⁺ long-range migration. To bridge this gap, we establish a consecutive Li⁺ transport pathway by integrating dissociating stators and conducting rotors within an amphidynamic COF (AD COF)-based p