Theory of ion chemical potentials in heterogeneous electrolyte environments

Electrochemical applications, ranging from energy storage to electrocatalysis and separations, involve ions in heterogeneous environments such as electrode/electrolyte interfaces, material interphases, and confined spaces. These environments influence ion thermodynamics through their effect on chemical potentials and, consequently, on the driving forces relevant to ion transport and electrochemical processes. In addition, features in bulk electrolytes, such as different ion sizes and valence asy