Aggregation-Mediated Cuprophilic Interactions Governing the Luminescence of a Cu 6 Nanocluster
Bao‐Liang Han·D. H. Sun·Zhennan Wu·Rishu Narwal·Vikas Tiwari·Rakesh Kumar Gupta·Tarak Karmakar·Zhi Wang·Chen-Ho Tung·Panpan Sun
Cuprophilic interactions are increasingly recognized as key determinants in the design of functional assemblies, particularly for enhancing luminescence. However, achieving precise control of cuprophilic interactions in self-assembled, atomically precise copper nanoclusters remains challenging. Here, we present a straightforward strategy to systematically modulate cuprophilic interactions through the supramolecular self-assembly of an atomically precise Cu(I) nanocluster, [Cu6(MBID)6] (Cu6, HMBI